I-Cathode Material
Ekulungiseni izinto ze-electrode ezingaphili zamabhethri e-lithium ion, ukusabela kwesimo esiqinile sokushisa okuphezulu yikona okuvame ukusetshenziswa kakhulu.Izinga lokushisa eliphezulu eliqinile lesigaba sokusabela: libhekisela enqubweni lapho izinto ezisabelayo ezihlanganisa izinto zesigaba esiqinile zisabela isikhathi esithile ezingeni lokushisa elithile futhi zikhiqize ukusabela kwamakhemikhali ngokuhlukana phakathi kwezakhi ezihlukahlukene ukuze kukhiqizwe izinhlanganisela eziqine kakhulu ezingeni lokushisa elithile. , okuhlanganisa ukusabela okuqinile-okuqinile, ukusabela kwegesi eqinile kanye nokusabela koketshezi oluqinile.
Ngisho noma indlela ye-sol-gel, indlela ye-coprecipitation, indlela ye-hydrothermal kanye nendlela ye-solvothermal isetshenziswa, ukusabela kwesigaba esiqinile noma i-solid-phase sintering ekushiseni okuphezulu kuyadingeka.Lokhu kungenxa yokuthi isimiso sokusebenza sebhethri ye-lithium-ion sidinga ukuthi impahla yayo ye-electrode ingafaka ngokuphindaphindiwe futhi isuse i-li +, ngakho-ke isakhiwo sayo se-lattice kufanele sibe nokuzinza okwanele, okudinga ukuthi i-crystallinity yezinto ezisebenzayo kufanele ibe phezulu futhi isakhiwo se-crystal kufanele sibe njalo. .Lokhu kunzima ukufeza ngaphansi kwezimo zokushisa eziphansi, ngakho-ke izinto ze-electrode zamabhethri e-lithium-ion asetshenziswa ngempela manje ngokuyisisekelo zitholakala ngokusabela kwe-high-temperature solid-state reaction.
I-cathode material processing processing line ikakhulukazi ihlanganisa uhlelo lokuxuba, uhlelo lwe-sintering, uhlelo lokuchoboza, uhlelo lokugeza amanzi (i-nickel ephezulu kuphela), uhlelo lokupakisha, uhlelo lokudlulisa impushana kanye nesistimu yokulawula ehlakaniphile.
Lapho inqubo yokuxuba emanzi isetshenziswa ekukhiqizeni izinto ze-cathode zamabhethri e-lithium-ion, izinkinga zokomisa zivame ukuhlangana nazo.Ama-solvents ahlukene asetshenziswa ekuxubeni okumanzi azoholela ezinkambisweni ezahlukene zokumisa kanye nemishini.Njengamanje, kunezinhlobo ezimbili eziyinhloko zezincibilikisi ezisetshenziswa ekuxubeni okumanzi: izincibilikisi ezingenawo amanzi, okuyizincibilikisi eziphilayo ezifana ne-ethanol, i-acetone, njll;I-solvent yamanzi.Imishini yokomisa yokuxuba okumanzi kwe-lithium-ion battery cathode materials ikakhulukazi ihlanganisa: vacuum rotary dryer, vacuum rake dryer, spray dryer, vacuum belt dryer.
Ukukhiqizwa kwezimboni zezinto ze-cathode zamabhethri e-lithium-ion ngokuvamile kusebenzisa inqubo ye-solid-state synthesis synthesis yezinga eliphezulu lokushisa, futhi umnyombo wayo kanye nemishini eyinhloko i-sintering kiln.Izinto zokusetshenziswa zokukhiqiza izinto ze-lithium-ion battery cathode zixutshwe ngokulinganayo futhi zomiswe, bese zilayishwa kuhhavini ukuze zifakwe emanzini, bese zithululwa kuhhavini zibe yinqubo yokuchotshozwa nokuhlukanisa.Ukuze kukhiqizwe izinto ze-cathode, izinkomba zobuchwepheshe nezomnotho ezifana nezinga lokushisa lokulawula izinga lokushisa, ukufana kwezinga lokushisa, ukulawulwa komkhathi nokufana, ukuqhubeka, amandla okukhiqiza, ukusetshenziswa kwamandla kanye ne-automation degree ye-ovini kubaluleke kakhulu.Njengamanje, imishini eyinhloko yokushisa esetshenziswa ekukhiqizeni izinto ze-cathode yi-pusher kiln, i-roller kiln kanye nesithando somlilo sensimbi.
◼ I-roller kiln iwuhubhe losayizi ophakathi nendawo enokufudumeza okuqhubekayo nokucwilisa.
◼ Ngokomkhathi wesithando somlilo, njenge-pusher kiln, i-roller kiln nayo ihlukaniswe yaba i-air kiln kanye ne-atmosphere.
- I-Air Kiln: ikakhulukazi esetshenziselwa izinto zokushisa ezidinga umoya we-oxidizing, njengezinto ze-lithium manganate, izinto ze-lithium cobalt oxide, izinto ze-ternary, njll;
- I-Atmosphere Kiln: ikakhulukazi esetshenziselwa izinto ze-NCA ternary, izinto ze-lithium iron phosphate (LFP), izinto ze-graphite anode nezinye izinto ezishisayo ezidinga umoya (njenge-N2 noma i-O2) ukuvikelwa kwegesi.
◼ I-roller kiln ithatha inqubo yokugingqa, ngakho ubude behhashi ngeke buthintwa amandla ashukumisayo.Ngokwethiyori, kungaba okungenamkhawulo.Izici zesakhiwo somgodi wesithando somlilo, ukungaguquguquki okungcono lapho kuqhunyiswa imikhiqizo, kanye nesakhiwo esikhulu sembobo yomlilo kulungele ukuhamba komoya esithandweni kanye nokukhipha amanzi kanye nokukhishwa kwenjoloba kwemikhiqizo.Ithuluzi elincanyelwayo lokuthatha indawo ye-pusher kiln ukuze uthole ukukhiqizwa okuphezulu ngempela.
◼ Njengamanje, i-lithium cobalt oxide, i-ternary, i-lithium manganate nezinye izinto ze-cathode zamabhethri e-lithium-ion zishiswa kuhhavini ye-roller emoyeni, kuyilapho i-lithium iron phosphate ifakwa kuhhavini ye-roller evikelwe i-nitrogen, futhi i-NCA ifakwe ku-roller. iziko elivikelwe umoya-mpilo.
I-Negative Electrode Material
Izinyathelo eziyinhloko zokugeleza kwenqubo eyisisekelo ye-graphite yokwenziwa zifaka phakathi ukwelashwa kwangaphambili, i-pyrolysis, ibhola lokugaya, i-graphitization (okungukuthi, ukwelashwa kokushisa, ukuze ama-athomu e-carbon ekuqaleni ahlelwe kahle ahlelwe kahle, kanye nezixhumanisi zobuchwepheshe ezibalulekile), ukuxuba, ukumboza, ukuxuba. ukuhlola, ukukala, ukupakisha kanye nokugcinwa kwempahla.Yonke imisebenzi ilungile futhi iyinkimbinkimbi.
◼ I-granulation ihlukaniswe ngenqubo ye-pyrolysis kanye nenqubo yokuhlola ibhola.
Enqubweni ye-pyrolysis, faka izinto ezimaphakathi 1 ku-reactor, shintsha umoya ku-reactor nge-N2, vala i-reactor, uyishise ngogesi ngokwejika lokushisa, uyinyakazise ku-200 ~ 300 ℃ i-1 ~ 3h, bese uqhubeka. ukuyishisisa ibe ngu-400 ~ 500 ℃, uyishukumise ukuze uthole impahla enosayizi wezinhlayiyana ezingu-10 ~ 20mm, wehlise izinga lokushisa futhi uyikhiphe ukuze uthole impahla ephakathi imishini ye-granulation, yomibili enesimiso esifanayo.Womabili ayanyakaza noma anyakaze ngaphansi kwejika elithile lokushisa ukuze aguqule ukwakheka kwezinto ezibonakalayo kanye nezakhiwo zamakhemikhali kureactor.Umehluko ukuthi igedlela elimile liyinhlanganisela yegedlela elishisayo neketela elibandayo.Izingxenye ze-material ku-kettle zishintshwa ngokuguquguquka ngokwejika lokushisa kugedlela elishisayo.Ngemva kokuphothula, ifakwa eketelani lokupholisa ukuze iphole, futhi igedlela elishisayo lingaphakelwa.Imishini ye-granulation eqhubekayo ibona ukusebenza okuqhubekayo, nokusetshenziswa kwamandla okuphansi nokuphuma okuphezulu.
◼ I-Carbonization kanye ne-graphitization yingxenye ebalulekile.Isithando somlilo se-carbonization sibeka izinto emazingeni okushisa aphakathi nendawo naphansi.Izinga lokushisa lomlilo we-carbonization lingafinyelela ku-1600 degrees Celsius, elingahlangabezana nezidingo ze-carbonization.Isilawuli sokushisa esihlakaniphile esiphezulu esiphezulu kanye nesistimu yokuqapha ye-PLC ezenzakalelayo izokwenza idatha ekhiqizwa inqubo ye-carbonization ilawulwe ngokunembile.
Isithando somlilo se-Graphitization, okuhlanganisa izinga lokushisa eliphezulu elivundlile, ukukhishwa okuphansi, okuqondile, njll., beka i-graphite endaweni eshisayo ye-graphite (indawo equkethe ikhabhoni) yokucwilisa nokuncibilikisa, futhi izinga lokushisa ngalesi sikhathi lingafinyelela ku-3200 ℃.
◼ Ukugqoka
Impahla emaphakathi engu-4 ithuthelwa kusisele ngohlelo lokudlulisa oluzenzakalelayo, futhi impahla igcwaliswa ngokuzenzakalela ku-promethium yebhokisi yi-manipulator.I-othomathikhi yokudlulisa uhlelo ihambisa ibhokisi le-promethium kwi-reactor eqhubekayo (i-roller kiln) ukuze ihlanganiswe, Thola impahla ephakathi 5 (ngaphansi kokuvikelwa kwe-nitrogen, impahla ishiselwa ku-1150 ℃ ngokusho kwejika elithile lokuphakama lokushisa kwe-8 ~ 10h. Inqubo yokushisa ukushisa imishini ngogesi, futhi indlela yokushisa ingaqondile Ukushisa kuguqula i-asphalt yekhwalithi ephezulu ebusweni bezinhlayiya ze-graphite zibe yi-pyrolytic carbon coating i-condense, futhi i-crystal morphology iyaguqulwa (isimo se-amorphous siguqulwa sibe yi-crystalline state), I-odered microcrystalline carbon layer yakhiwa phezu kwezinhlayiya ze-graphite zemvelo eziyindilinga, futhi ekugcineni i-graphite eboshwe njengempahla enesakhiwo "segobolondo eliyinhloko" etholiwe